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我国黑色金属资源发展形势研判

“黑色金属矿产资源强国战略研究”专题组

《中国工程科学》 2019年 第21卷 第1期   页码 97-103 doi: 10.15302/J-SSCAE-2019.01.014

摘要:

作为供给侧结构性改革的先行者,中国钢铁行业积极化解过剩产能,彻底取缔“地条钢”,2016—2017年化解钢铁产能超过1.2×108t,清除“地条钢”等违法产能1.4×108t。当前,全球钢铁工业处于产能过剩周期,中国钢铁消费由持续增长向“峰值平台区”转变,单位GDP粗钢消费强度回落,单位投资粗钢消费强度下降,预计到2025年国内粗钢消费需求量为6×108~6.5×108t,产量为6.5×108~7.0×108t,到2030年,国内粗钢消费需求量为5.3×108~6.0×108t,产量为5.9×108~6.5×108 t。与此同时,我国废钢资源供给量将快速增加,未 来充足的废钢资源将是我国钢铁工业强有力的支撑,铁素资源构成也将发生重大变化,国际铁矿石资源的需求量将逐步下降,同时对于推动生态文明建设和绿色发展具有重要作用。

关键词: 钢铁     废钢     铁矿石     峰值平台区    

Effects of Fe(II) on anammox community activity and physiologic response

Jing Ding, Wanyi Seow, Jizhong Zhou, Raymond Jianxiong Zeng, Jun Gu, Yan Zhou

《环境科学与工程前沿(英文)》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1299-9

摘要: Abstract • 0.12 mmol/L Fe(II) enhanced the total anammox activity and bacterial abundance best. • 0.09 mmol/L Fe(II) led to the best performance on relative anammox activity. • 0.75 mmol/L Fe(II) had an immediate but recoverable inhibition on anammox activity. • More genes but not relative level were expressed at higher Fe(II) concentration. Though there are many literatures studying the effects of iron on anammox process, these studies only focus on the reactor performance and/or the microbial community changes, the detailed effects and mechanisms of Fe(II) on anammox bacterial activity and physiology have not been explored. In this study, four Fe(II) concentrations (0.03, 0.09, 0.12 and 0.75 mmol/L) were employed into the enriched anammox culture. The enhancement and inhibition effects of Fe(II) on anammox process and bacterial physiology were investigated. It was discovered that the anammox process and bacterial growth were enhanced by 0.09 and 0.12 mmol/L Fe(II), in which the 0.12 mmol/L Fe(II) had advantage in stimulating the total anammox activity and bacterial abundance, while 0.09 mmol/L Fe(II) enhanced the relative anammox activity better. The anammox activity could be inhibited by 0.75 mmol/L Fe(II) immediately, while the inhibition was recoverable. Both 0.09 and 0.12 mmol/L Fe(II) induced more genes being expressed, while didn’t show a stimulation on the relative expression level of functional genes. And anammox bacteria showed a stress response to detoxify the Fe inhibition once inhibited by 0.75 mmol/L Fe(II). This study provides more information about physiologic response of anammox bacteria to external influence (enhancement and inhibition), and may also instruct the future application of anammox process in treating various sources of wastewater (containing external disturbances such as heavy metals) and/or different treatment strategies (e.g. from side-stream to main-stream).

关键词: Anaerobic ammonium oxidation (Anammox)     Candidatus Kuenenia stuttgartiensis     Ferrous iron     GeoChip    

Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate

《化学科学与工程前沿(英文)》 2023年 第17卷 第4期   页码 460-469 doi: 10.1007/s11705-022-2224-5

摘要: Nitric oxide being a major gas pollutant has attracted much attention and various technologies have been developed to reduce NO emission to preserve the environment. Advanced persulfate oxidation technology is a workable and effective choice for wet flue gas denitrification due to its high efficiency and green advantages. However, NO absorption rate is limited and affected by mass transfer limitation of NO and aqueous persulfate in traditional reactors. In this study, a rotating packed bed (RPB) was employed as a gas–liquid absorption device to elevate the NO removal efficiency (ηNO) by aqueous persulfate ((NH4)2S2O8) activated by ferrous ethylenediaminetetraacetate (Fe2+-EDTA). The experimental results regarding the NO absorption were obtained by investigating the effect of various operating parameters on the removal efficiency of NO in RPB. Increasing the concentration of (NH4)2S2O8 and liquid–gas ratio could promoted the oxidation and absorption of NO while the ηNO decreased with the increase of the gas flow and NO concentration. In addition, improving the high gravity factor increased the ηNO and the total volumetric mass transfer coefficient (KGα) which raise the ηNO up to more than 75% under the investigated system. These observations proved that the RPB can enhance the gas–liquid mass transfer process in NO absorption. The correlation formula between KGα and the influencing factors was determined by regression calculation, which is used to guide the industrial scale-up application of the system in NO removal. The presence of O2 also had a negative effect on the NO removal process and through electron spin resonance spectrometer detection and product analysis, it was revealed that Fe2+-EDTA activated (NH4)2S2O8 to produce •SO4, •OH and •O2, played a leading role in the oxidation of NO, to produce NO3 as the final product. The obtained results demonstrated a good applicable potential of RPB/PS/Fe2+-EDTA in the removal of NO from flue gases.

关键词: rotating packed bed     Fe2+-EDTA     sulfate radical     hydroxyl radical     NO removal efficiency    

Enhanced carbon tetrachloride degradation by hydroxylamine in ferrous ion activated calcium peroxide

Wenchao Jiang, Ping Tang, Zhen Liu, Huan He, Qian Sui, Shuguang Lyu

《环境科学与工程前沿(英文)》 2020年 第14卷 第2期 doi: 10.1007/s11783-019-1197-1

摘要: Complete CT degradation was achieved by employing HA to CP/Fe(II)/FA process. Quantitative detection of Fe(II) regeneration and HO• production was investigated. Benzoic acid outcompeted FA for the reaction with HO•. CO2•− was the dominant reductive radical for CT removal. Effects of solution matrix on CT removal were conducted. Hydroxyl radicals (HO•) show low reactivity with perchlorinated hydrocarbons, such as carbon tetrachloride (CT), in conventional Fenton reactions, therefore, the generation of reductive radicals has attracted increasing attention. This study investigated the enhancement of CT degradation by the synergistic effects of hydroxylamine (HA) and formic acid (FA) (initial [CT] = 0.13 mmol/L) in a Fe(II) activated calcium peroxide (CP) Fenton process. CT degradation increased from 56.6% to 99.9% with the addition of 0.78 mmol/L HA to the CP/Fe(II)/FA/CT process in a molar ratio of 12/6/12/1. The results also showed that the presence of HA enhanced the regeneration of Fe(II) from Fe(III), and the production of HO• increased one-fold when employing benzoic acid as the HO• probe. Additionally, FA slightly improves the production of HO•. A study of the mechanism confirmed that the carbon dioxide radical (CO2•−), a strong reductant generated by the reaction between FA and HO•, was the dominant radical responsible for CT degradation. Almost complete CT dechlorination was achieved in the process. The presence of humic acid and chloride ion slightly decreased CT removal, while high doses of bicarbonate and high pH inhibited CT degradation. This study helps us to better understand the synergistic roles of FA and HA for HO• and CO2•− generation and the removal of perchlorinated hydrocarbons in modified Fenton systems.

关键词: Calcium peroxide     Hydroxylamine     Modified Fenton     Reactive oxygen species     Perchlorinated hydrocarbon    

randomized, controlled, open label non-inferiority trial of intravenous ferric carboxymaltose versus ironsucrose in patients with iron deficiency anemia in China

《医学前沿(英文)》 doi: 10.1007/s11684-023-1001-2

摘要: Iron deficiency (ID) and ID anemia (IDA) pose significant public health concerns in China. Although iron sucrose (IS) treatment is well-established in the country, ferric carboxymaltose (FCM) offers the advantage of higher doses and fewer infusions. This open label, randomized, controlled, non-inferiority trial was conducted at multiple sites in China to compare the outcomes of FCM (maximum of 2 doses, 500 or 1000 mg iron) and IS (up to 11 infusions, 200 mg iron) treatments in subjects with IDA. The primary endpoint was the achievement of hemoglobin (Hb) response (an increase of ≥2 g/dL from baseline) within 8 weeks, whereas secondary endpoints included changes in Hb, transferrin saturation, and serum ferritin levels. Among the 371 randomized subjects, a similar percentage of subjects treated with FCM and IS achieved Hb-response (FCM 99.4%, IS 98.3%), thereby confirming the non-inferiority of FCM compared with IS (difference 1.12 (−2.15, 4.71; 95% confidence interval (CI))). Furthermore, a significantly higher proportion of FCM-treated subjects achieved early Hb-response at Week 2 (FCM 85.2%, IS 73.2%; difference 12.1 (3.31, 20.65; 95% CI)). Additionally, the increase in TSAT and serum ferritin levels from baseline was significantly greater at all time points for FCM-treated subjects. The safety profiles of FCM and IS were comparable, with the exception of transient hypophosphatemia and pyrexia, which are consistent with FCM’s known safety profile. In conclusion, FCM proves to be an efficacious treatment for IDA, providing faster Hb-response and correction of ID with fewer administrations than IS.

关键词: iron deficiency     anemia     intravenous iron     ferric carboxymaltose     iron sucrose     Hb response     early response    

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosionin cast iron pipes

《环境科学与工程前沿(英文)》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1506-3

摘要:

• The early corrosion process in the cast iron pipes was investigated.

关键词: Cast iron pipe corrosion     Drinking water distribution systems     Chlorine disinfection     Iron-oxidizing bacteria     Coupling effects    

Performance of iron-air battery with iron nanoparticle-encapsulated C–N composite electrode

《能源前沿(英文)》 doi: 10.1007/s11708-023-0913-5

摘要: Highly efficient and stable iron electrodes are of great significant to the development of iron-air battery (IAB). In this paper, iron nanoparticle-encapsulated C–N composite (NanoFe@CN) was synthesized by pyrolysis using polyaniline as the C–N source. Electrochemical performance of the NanoFe@CN in different electrolytes (alkaline, neutral, and quasi-neutral) was investigated via cyclic voltammetry (CV). The IAB was assembled with NanoFe@CN as the anode and IrO2 + Pt/C as the cathode. The effects of different discharging/charging current densities and electrolytes on the battery performance were also studied. Neutral K2SO4 electrolyte can effectively suppress the passivation of iron electrode, and the battery showed a good cycling stability during 180 charging/discharging cycles. Compared to the pure nano-iron (NanoFe) battery, the NanoFe@CN battery has a more stable cycling stability either in KOH or NH4Cl + KCl electrolyte.

关键词: energy storage and conversion     metallic composites     nanocomposites     iron-air battery     iron anode    

Redox reactions of iron and manganese oxides in complex systems

Jianzhi Huang, Huichun Zhang

《环境科学与工程前沿(英文)》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1255-8

摘要: • Mechanisms of redox reactions of Fe- and Mn-oxides were discussed. • Oxidative reactions of Mn- and Fe-oxides in complex systems were reviewed. • Reductive reaction of Fe(II)/iron oxides in complex systems was examined. • Future research on examining the redox reactivity in complex systems was suggested. Conspectus Redox reactions of Fe- and Mn-oxides play important roles in the fate and transformation of many contaminants in natural environments. Due to experimental and analytical challenges associated with complex environments, there has been a limited understanding of the reaction kinetics and mechanisms in actual environmental systems, and most of the studies so far have only focused on simple model systems. To bridge the gap between simple model systems and complex environmental systems, it is necessary to increase the complexity of model systems and examine both the involved interaction mechanisms and how the interactions affected contaminant transformation. In this Account, we primarily focused on (1) the oxidative reactivity of Mn- and Fe-oxides and (2) the reductive reactivity of Fe(II)/iron oxides in complex model systems toward contaminant degradation. The effects of common metal ions such as Mn2+ , Ca2+, Ni2+, Cr3+ and Cu2+, ligands such as small anionic ligands and natural organic matter (NOM), and second metal oxides such as Al, Si and Ti oxides on the redox reactivity of the systems are briefly summarized.

关键词: Iron oxides     manganese oxides     reduction     oxidation     complex systems     reaction kinetics and mechanisms    

Mechanical properties of vanadium-alloyed austempered ductile iron for crankshaft applications

《机械工程前沿(英文)》 2023年 第18卷 第3期 doi: 10.1007/s11465-023-0746-2

摘要: This study focused on the development of austempered ductile iron (ADI) with desirable combination of mechanical properties for crankshaft applications by the combined effect of vanadium (V) alloying and an optimized heat treatment process. The produced unalloyed GGG60, 0.15% V-alloyed GGG60 (V-15), and 0.30% V-alloyed GGG60 samples were subjected to austenitizing at 900 °C for 1 h and subsequent austempering processes at 250, 300, and 350 °C for 15, 30, 60, 90, and 180 min. As a result of these austempering processes, different bainitic structures were obtained, which led to the formation of diverse combinations of mechanical properties. The mechanical properties of the austempered samples were tested comprehensively, and the results were correlated with their microstructures and the stability of the retained austenite phases. From the microstructural observations, the V-alloyed samples exhibited a finer microstructure and a more acicular ferrite phase than unalloyed samples. The V addition delayed the coarsening of the acicular ferrite structures and considerably contributed to the improvement of the mechanical properties of GGG60. Moreover, the X-ray diffraction results revealed that the retained austenite volume and the carbon enrichment of austenite phases in ADI samples were remarkably affected by the addition of vanadium. The increase in volume fraction of retained austenite and its carbon content provided favorable ductility and toughness to V-15, as confirmed by the elongation and impact test results. Consequently, the dual-phase ausferrite microstructure of V-15 that was austempered at 300 °C for 60 min exhibited high strength with substantial ductility and toughness for crankshaft applications.

关键词: austempered ductile iron (ADI)     vanadium alloying     mechanical properties     crankshafts     retained austenite    

Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1358-2

摘要:

• Microbes enhance denitrification under varying DO concentrations and SIF dosages.

关键词: Scrap iron filing     Nitrate removal     Phosphate removal     Mixed culture denitrification     Zero valent iron    

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

《化学科学与工程前沿(英文)》 2023年 第17卷 第6期   页码 749-758 doi: 10.1007/s11705-022-2261-0

摘要: Since lithium iron phosphate cathode material does not contain high-value metals other than lithium, it is therefore necessary to strike a balance between recovery efficiency and economic benefits in the recycling of waste lithium iron phosphate cathode materials. Here, we describe a selective recovery process that can achieve economically efficient recovery and an acceptable lithium leaching yield. Adjusting the acid concentration and amount of oxidant enables selective recovery of lithium ions. Iron is retained in the leaching residue as iron phosphate, which is easy to recycle. The effects of factors such as acid concentration, acid dosage, amount of oxidant, and reaction temperature on the leaching of lithium and iron are comprehensively explored, and the mechanism of selective leaching is clarified. This process greatly reduces the cost of processing equipment and chemicals. This increases the potential industrial use of this process and enables the green and efficient recycling of waste lithium iron phosphate cathode materials in the future.

关键词: lithium iron phosphate powder     stoichiometric number     selective leaching     lithium recovery    

Synthesis of iron(II) complexes with asymmetric N

Wolfgang Bauer, Tanja Ossiander, Birgit Weber

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 400-408 doi: 10.1007/s11705-018-1753-4

摘要:

The synthesis of new Schiff base-like ligands with asymmetric substituents pattern and their iron complexes with pyridine as axial ligand is described. Two of the ligands and one of the iron(II) complexes were characterized by single crystal X-ray structure analysis. One of the the iron(II) complexes shows spin crossover behavior while the others remain in the high spin state. The influence of the reduced symmetry of the ligand on the properties of the complexes is discussed.

关键词: iron     Schiff base-like ligands     magnetism     spin crossover     X-ray structures    

Methanol to propylene: the effect of iridium and iron incorporation on the HZSM-5 catalyst

Alireza MOHAMMADREZAEI, Sadegh PAPARI, Mousa ASADI, Abas NADERIFAR, Reza GOLHOSSEINI

《化学科学与工程前沿(英文)》 2012年 第6卷 第3期   页码 253-258 doi: 10.1007/s11705-012-0902-4

摘要: The effect of iridium and iron impregnation of HZSM-5 zeolite on the methanol to propylene reaction (MTP) was investigated. The selectivities of propylene and other hydrocarbons, and the conversion of methanol were compared by performing MTP in a small pilot plant. The results indicate that HZSM-5 zeolite modified by iron and iridium increased propylene selectivity by 6.3% and 8%, respectively. The selectivity of propylene was higher for Ir/H-ZSM-5 than for Fe/H-ZSM-5, where Fe/H-ZSM-5 was more stable than Ir/H-ZSM-5. Analytic techniques, including X-ray diffraction, BET surface area, temperature-programmed desorption of ammonia, and inductively coupled plasma atomic emission spectroscopy, were used to characterize the modified zeolites as well as the parent zeolites.

关键词: HZSM-5     promoter     iridium     iron     MTP    

Continuous dynamic monitoring of a centenary iron bridge for structural modification assessment

Carmelo GENTILE,Antonella SAISI

《结构与土木工程前沿(英文)》 2015年 第9卷 第1期   页码 26-41 doi: 10.1007/s11709-014-0284-4

摘要: A multi-channel continuous dynamic monitoring system has been installed in a centenary iron arch bridge on late November 2011. The historic infrastructure, completed in 1889 and crossing the Adda river about 50 km far from Milan, is the most important monument of XIX century iron architecture in Italy and is still used as roadway and railway bridge. The monitoring project follows a series of preliminary ambient vibration tests carried out on the bridge since June 2009. The paper describes the bridge structure and its dynamic characteristics identified from the experimental studies developed since 2009, the installed monitoring system and the software developed in LabVIEW for automatically processing the collected data. Subsequently, the tracking of automatically identified natural frequencies over a period of about 18 months is presented and discussed, highlighting the effects of environmental and operational conditions on the bridge dynamic characteristics as well as the detection of structural changes, mainly based on natural frequencies shifts.

关键词: automated modal identification     continuous dynamic monitoring     environmental/operational effects     iron arch bridge     structural health monitoring    

Comparison of different valent iron on anaerobic sludge digestion: Focusing on oxidation reduction potential

《环境科学与工程前沿(英文)》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1514-3

摘要:

• ORP value from −278.71 to −379.80 mV showed indiscernible effects on methane yield.

关键词: Enhanced anaerobic sludge digestion     Different iron valence     Oxidation reduction potential     Dissolved organic nitrogen     Microbial community    

标题 作者 时间 类型 操作

我国黑色金属资源发展形势研判

“黑色金属矿产资源强国战略研究”专题组

期刊论文

Effects of Fe(II) on anammox community activity and physiologic response

Jing Ding, Wanyi Seow, Jizhong Zhou, Raymond Jianxiong Zeng, Jun Gu, Yan Zhou

期刊论文

Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate

期刊论文

Enhanced carbon tetrachloride degradation by hydroxylamine in ferrous ion activated calcium peroxide

Wenchao Jiang, Ping Tang, Zhen Liu, Huan He, Qian Sui, Shuguang Lyu

期刊论文

randomized, controlled, open label non-inferiority trial of intravenous ferric carboxymaltose versus ironsucrose in patients with iron deficiency anemia in China

期刊论文

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosionin cast iron pipes

期刊论文

Performance of iron-air battery with iron nanoparticle-encapsulated C–N composite electrode

期刊论文

Redox reactions of iron and manganese oxides in complex systems

Jianzhi Huang, Huichun Zhang

期刊论文

Mechanical properties of vanadium-alloyed austempered ductile iron for crankshaft applications

期刊论文

Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

期刊论文

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

期刊论文

Synthesis of iron(II) complexes with asymmetric N

Wolfgang Bauer, Tanja Ossiander, Birgit Weber

期刊论文

Methanol to propylene: the effect of iridium and iron incorporation on the HZSM-5 catalyst

Alireza MOHAMMADREZAEI, Sadegh PAPARI, Mousa ASADI, Abas NADERIFAR, Reza GOLHOSSEINI

期刊论文

Continuous dynamic monitoring of a centenary iron bridge for structural modification assessment

Carmelo GENTILE,Antonella SAISI

期刊论文

Comparison of different valent iron on anaerobic sludge digestion: Focusing on oxidation reduction potential

期刊论文